A Laboratory Study of High-Temperature Corrosion on Fireside Surfaces of Coal-Fired Steam Generators

[+] Author and Article Information
S. A. Goldberg, J. J. Gallagher, A. A. Orning

Pittsburgh Coal Research Center, Bureau of Mines, U. S. Department of the Interior, Pittsburgh, Pa.

J. Eng. Power 90(2), 193-198 (Apr 01, 1968) (6 pages) doi:10.1115/1.3609162 History: Received August 17, 1967; Online August 25, 2011


Three experimental approaches gave significant information on high-temperature fireside corrosion: 1 Sodium and potassium chlorides, injected through a gas flame, were deposited as such and then converted to sulfates on an iron surface. 2 Samples of mixed alkali and iron sulfates first showed decomposition and then formed melts at temperatures as low as 1070 deg F. This temperature is within the range that might be expected for fireside surface temperatures on superheater and reheater tubes of large steam generators. 3 Alkali metal chlorides and sulfates, in partial coverage of metal disks and in a flue gas atmosphere, formed fused deposits at temperatures as low as 900 deg F. Complex alkali iron sulfates may cause corrosion either by direct electrolytic corrosion or by altering the normally protective iron oxide scale so that the metal is exposed to direct oxidative corrosion.

Copyright © 1968 by ASME
Your Session has timed out. Please sign back in to continue.





Some tools below are only available to our subscribers or users with an online account.

Related Content

Customize your page view by dragging and repositioning the boxes below.

Related Journal Articles
Related eBook Content
Topic Collections

Sorry! You do not have access to this content. For assistance or to subscribe, please contact us:

  • TELEPHONE: 1-800-843-2763 (Toll-free in the USA)
  • EMAIL: asmedigitalcollection@asme.org
Sign In