Cost considerations are the decisive factor for the market launch of PEFCs. This benchmark comparison first focuses on material costs for the basic chemicals involved in the ionomer syntheses. A new way of generating company-independent cost information on raw chemicals is therefore used. Secondly, an estimate is given of how the complexity of the chemical plant entails additional production costs. This has been done by applying five different approaches developed by process engineers in order to appraise the plants' grass roots investments. Finally, US$m2 is a decisive figure for membranes. The values obtained demonstrate the viability of future widespread use.

1.
Ise
,
M.
,
Schmidt
,
H.
, and
Waidhas
,
M.
, 2001, “
Materials and Construction Principles for PEM Fuel Cells
,”
Proc. 1st European PEFC Forum Conference
,
Lucerne
, pp.
285
295
.
2.
Carlson
,
E.
et al.
, 2001, “
Cost Analysis of Fuel Cell System for Transportation
,” Arthur D. Little Report, Argonne National Lab., Dept. of Energy.
3.
Choi
,
W. C.
,
Kim
,
J. D.
, and
Woo
,
S. I.
, 2001, “
Modification of Proton Conducting Membrane for Reducing Methanol Crossover in a Direct-Methanol Fuel Cell
,”
J. Power Sources
0378-7753,
96
(
2
), pp.
411
414
.
5.
Anilkumar
,
R.
, and
Burton
,
D. J.
, 2002, “
A Remarkable Room Temperature Preparation of the Trifluorovinylzinc Reagent From HFC-134a. A Cost-Effective, High-Yield Synthesis of α, β, β-Trifluorostyrenes
,”
Tetrahedron
0040-4020,
43
, pp.
2731
2733
.
6.
Heinze
,
P. L.
, and
Burton
,
D. J.
, 1988, “
Palladium-Catalyzed Cross-Coupling of Perfluoroalkenylzinc Reagents With Aryl Lodides. A New, Simple Synthesis of α, β, β-Trifluorostyrenes and the Stereoselective Preparation of 1-Arylperfluoropropenes
,”
J. Org. Chem.
0022-3263,
53
, pp.
2714
2720
.
7.
Jones
,
D. J.
, and
Rozière
,
J.
, 2001, “
Recent Advances in the Functionalization of Polybenzimidazole and Polyetherketone for Fuel Cell Applications
,”
J. Membr. Sci.
,
185
, pp.
41
58
.
8.
Grot
,
W. G.
, 1994, “
Polymerization of Fluorinated Copolymers
,” US Patent 5,281,680.
9.
Resnick
,
P. R.
, 1978, “
Purification of Perfluorosulfonyl Fluoride Perfluorovinyl Ethers by Thermal Decomposition of Unstable Isomers
,” US Reissued Patent Re. 29,534.
10.
Ikeda
,
M.
,
Miura
,
M.
, and
Aoshima
,
A.
, 1990, “
Process for the Production of Hexafluoropropylene Oxide
,” US Patent 4,925,961.
11.
Putnam
,
R. E.
, and
Nicoll
,
W. D.
, 1967, “
Fluorocarbon Ethers Containing Sulfonyl Groups
,” US Patent 3,301,893.
12.
England
,
D. C.
, 1958, “
α-Sulfopolyfluoromonocarboxylic Acids and Derivatives Hydrolyzable Thereto
,” US Patent 2,852,554.
13.
Bowden
,
R. D.
,
Burgess
,
L.
, and
Clark
,
R. J.
, 1981, “
Preparation of Aromatic Fluoro-Compounds
,” US Patent 4,263,458.
14.
Rose
,
J. A.
, and
Staniland
,
P. A.
, 1982, “
Thermoplastic Aromatic Polyetherketones
,” US Patent 4,320,224.
15.
Staniland
,
P. A.
, 1988, “
Thermoplastic Aromatic Polyetherketones
,” US Patent 4,717,761.
16.
Staniland
,
P.
,
Gilbert
,
A. H.
, and
Henderson
,
I. R. M.
, 1991, “
Production and/or Handling of Aryl Polyethers and Thioethers Polymers
,” US Patent 5,051,495.
17.
Ulrich
,
H. H.
, and
Rafler
,
G.
, 1998, “
Sulfonated Polyaryl Ether Ketones
,” Die Angewandte Makromolekulare Chemie
263
, pp.
71
78
.
18.
Vorwerk
,
E.
, 1993, “
Process for the Production of Pure 3,3′,4,4′-Tetraamino-Biphenyl
,” US Patent 5,235,105.
19.
Cawse
,
J. N.
, 1988, “
Process for the Production of Substantially Monoester-Free Diaryl Esters of Aromatic Dicarboxylic Acids
,” US Patent 4,737,569.
20.
Choe
,
E. W.
, and
Conciatori
,
A. B.
, 1984, “
Two Stage Melt Production of High Molecular Weight Polybenzimidazoles with Phosphorous Catalyst
,” US Patent 4,485,232.
21.
Calundann
,
G.
, et al.
, 2002, “
Protonenleitende Membran und deren Verwendung
,” German Patent DE 10117687A1.
22.
Morrison
,
R. C.
,
Hall
,
R. W.
, and
Rathman
,
T. L.
, 1986, “
Stable Lithium Diisopropylamide and Method of Preparation
,” US Patent 4,595,779.
23.
Corella
,
J. A.
, 2001, “
Method of Preparation of Alkali-Metal Amides
,” US Patent 6,169,203.
24.
Paparatto
,
G.
, 1985, “
Method for the Synthesis of Iodobenzene
,” European Patent EP 0183579A1.
25.
Marhold
,
A.
, and
Klauke
,
E.
, 1979, “
M-Bromo-benzotrifluorides
,” US Patent 4,155,940.
26.
Stone
,
C.
,
Steck
,
A. E.
, and
Lousenberg
,
R. D.
, 1997, “
Substituted Trifluorostyrene Monomeric Compositions
,” US Patent 5,684,192.
27.
Stone
,
C.
,
Steck
,
A. E.
, and
Wei
,
J.
, 1998, “
Trifluorostyrene and Substituted Trifluorostyrene Copolymeric Compositions and Ion-Exchange Membranes Formed Therefrom
,” US Patent 5,773,480.
28.
Steck
,
A. E.
, and
Stone
,
C.
, 2002, “
α, α, β-trifluorostyrene-Based Composite Membranes
,” US Patent 6,437,011.
29.
Zevnik
,
F. C.
, and
Buchanan
,
R. L.
, 1963, “
Generalized Correlation of Process Investment
,”
Chem. Eng. Prog.
0360-7275,
59(2)
, pp.
70
77
.
30.
Stallworthy
,
E. A.
, 1970, “
The Viewpoint of a Large Chemical Manufacturing Company
,”
Chem. Eng. Prog.
0360-7275,
239
, pp.
CE182
CE189
.
31.
Wilson
,
G. T.
, 1971, “
Capital Investment for Chemical Plant
,”
Brit. Chem. Eng. Proc. Techn.
,
16
(10), pp.
931
934
.
32.
Allen
,
D. H.
, and
Page
,
R. C.
, 1975, “
Revised Technique for Predesign Cost Estimating
,”
Chem. Eng.
,
82
(5), pp.
142
150
.
33.
Taylor
,
J. H.
, 1977, “
The ‘Process Step Scoring’ Method for Making Quick Capital Estimates
,”
Eng. and Proc. Econ.
,
2
, pp.
259
267
.
34.
Gebert
,
M.
, 2004, “
Benchmark-Methodik für Komponenten in Polymerelektrolyt-Brennstoffzellen
,”
Schriften des Forschungszentrums Jülich
, Energy Technology 30–ISBN 3-89336-355-6. www.fz-juelich and de/zb/Publishing̱Housewww.fz-juelich and de/zb/Publishing̱House.
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