In this study, the performance of a polymer electrolyte membrane fuel cell with double-side microporous layer (MPL) coating on gas diffusion layer (GDL) is investigated experimentally. A standard commercial SGL® 10BA carbon paper is used as the substrate and it is coated with MPL on both sides of the paper with different composition. Three different carbon powders are used in the experiments, including Vulcan XC-72R, Acetylene black, and Black Pearls 2000. The effect of polytetrafluoroethylene (PTFE) content is also considered. A single cell testing apparatus is constructed to measure the cell performance and evaluate the effect of GDL with double-side MPL coating. Accordingly, the optimal fabrication parameters of double-side MPL are determined. The result shows that under the same operating conditions, the performance of fuel cell using GDL with double-side MPL is better than that using general single-side MPL. The Acetylene black is found to give the best cell performance than the others. The optimal composition of MPL on the surfaces facing to the catalyst layer and flow-channel plate are 1.25 mg/cm2 and 0.25 mg/cm2, respectively. Besides, the optimal PTFE content is the same on both sides of MPL which is found to be 20 wt%.

References

1.
Jordan
,
L. R.
,
Shukla
,
A. K.
,
Behrsing
,
T.
,
Avery
,
N. R.
,
Muddle
,
B. C.
, and
Forsyth
,
M.
,
2000
, “
Diffusion Layer Parameters Influencing Optimal Fuel Cell Performance
,”
J. Power Sources
,
86
, pp.
250
254
.10.1016/S0378-7753(99)00489-9
2.
Antolini
,
E.
,
Passos
,
R. R.
, and
Ticianelli
,
E. A.
,
2002
, “
Effects of the Carbon Powder Characteristics in the Cathode Gas Diffusion Layer on the Performance of Polymer Electrolyte Fuel Cells
,”
J. Power Sources
,
109
, pp.
477
482
.10.1016/S0378-7753(02)00112-X
3.
Lim
,
C.
, and
Wang
,
C. Y.
,
2004
, “
Effects of Hydrophobic Polymer Content in GDL on Power Performance of a PEM Fuel Cell
,”
Electrochim. Acta
,
49
, pp.
4149
4156
.10.1016/j.electacta.2004.04.009
4.
Park
,
G. G.
,
Sohn
,
Y. J.
,
Yang
,
T. H.
,
Yoon
,
Y. G.
,
Lee
,
W. Y.
, and
Kim
,
C. S.
,
2004
, “
Effect of PTFT Contents in the Gas Diffusion Media on the Performance of PEMFC
,”
J. Power Sources
,
131
, pp.
182
187
.10.1016/j.jpowsour.2003.12.037
5.
Williams
,
M. V.
,
Begg
,
E.
,
Bonville
,
L.
,
Kunz
,
H. R.
, and
Fenton
,
J. M.
,
2004
, “
Characterization of Gas Diffusion Layers for PEMFC
,”
J. Electrochem. Soc.
,
151
, pp.
1173
1180
.10.1149/1.1764779
6.
Williams
,
M. V.
,
Kunz
,
H. R.
, and
Fenton
,
J. M.
,
2004
, “
Influence of Convection Through Gas-Diffusion Layers on Limiting Current in OEM FCs Using a Serpentine Flow Field
,”
J. Electrochem. Soc.
,
151
, pp.
1617
1627
.10.1149/1.1789791
7.
Yu
,
J.
,
Islam
,
M. N.
,
Matsuura
,
T.
,
Tamano
,
M.
,
Hayashi
,
Y.
, and
Hori
,
N.
,
2005
, “
Improving the Performance of a PEMFC With Ketjenblack EC-600JD Carbon Black as the Material of the Microporous Layer
,”
J. Electrochem. Soc.
,
8
, pp. A320–A323.10.1149/1.1904504
8.
Escribano
,
S.
,
Blachot
,
J. F.
,
Etheve
,
J.
,
Morin
,
A.
, and
Mosdale
,
R.
,
2006
, “
Characterization of PEMFCs Gas Diffusion Layers Properties
,”
J. Power Source
,
156
, pp.
8
13
.10.1016/j.jpowsour.2005.08.013
9.
Park
,
S.
,
Lee
,
J. W.
, and
Popov
,
B. N.
,
2006
, “
Effect of Carbon Loading in Microporous Layer on PEM Fuel Cell Performance
,”
J. Power Source
,
163
, pp.
357
363
.10.1016/j.jpowsour.2006.09.020
10.
Wang
,
X. L.
,
Zhang
,
H. M.
,
Zhang
,
J. L.
,
Xu
,
H. F.
,
Tian
,
Z. Q.
,
Chen
,
J.
,
Zhong
,
H. X.
,
Liang
,
Y. M.
, and
Ti
,
B. L.
,
2006
, “
Micro-Porous Layer With Composite Carbon Black for PEM Fuel Cells
,”
Electrochim. Acta
,
51
, pp.
4909
4915
.10.1016/j.electacta.2006.01.048
11.
Wang
,
X.
,
Zhang
,
H.
,
Zhang
,
J.
,
Xu
,
H.
,
Zhu
,
X.
,
Chen
,
J.
, and
Yi
,
B.
,
2006
, “
A Bi-Functional Micro-Porous Layer With Composite Carbon Black for PEM Fuel Cells
,”
J. Power Sources
,
162
, pp.
474
479
.10.1016/j.jpowsour.2006.06.064
12.
Atiyeh
,
H. K.
,
Karan
,
K.
,
Peppley
,
B.
,
Phoenix
,
A.
,
Halliop
,
E.
, and
Pharoah
,
J.
,
2007
, “
Experimental Investigation of the Role of a Microporous Layer on the Water Transport and Performance of a PEM Fuel Cell
,”
J. Power Sources
,
170
, pp.
111
121
.10.1016/j.jpowsour.2007.04.016
13.
Tang
,
H.
,
Wang
,
S.
,
Pan
,
M.
, and
Yuan
,
R.
,
2007
, “
Porosity-Graded Micro-Porous Layers for Polymer Electrolyte Membrane Fuel Cells
,”
J. Power Sources
,
166
, pp.
41
46
.10.1016/j.jpowsour.2007.01.021
14.
Karan
,
K.
,
Atiyeh
,
H.
,
Phoenix
,
A.
,
Halliop
,
E.
,
Pharoah
,
J.
, and
Peppley
,
B.
,
2007
, “
An Experimental Investigation of Water Transport in PEMFCs: The Role of Microporous Layers
,”
J. Electrochem. Soc.
,
10
, pp. B34–B38.10.1149/1.2398728
15.
Yan
,
W. M.
,
Hsueh
,
C. Y.
,
Soong
,
C. Y.
,
Chen
,
F.
,
Cheng
,
C. H.
, and
Mei
,
S. C.
,
2007
, “
Effects of Fabrication Processes and Material Parameters of GDL on Cell Performance of PEM Fuel Cell
,”
Int. J. Hydrogen Energy
,
32
, pp.
4452
4458
.10.1016/j.ijhydene.2007.02.003
16.
Lin
,
J. H.
,
Chen
,
W. H.
,
Su
,
Y. J.
, and
Ko
,
T. H.
,
2008
, “
Performance Analysis of a Proton-Exchange Membrane Fuel Cell (PEMFC) With Various Hydrophobic Agents in a Gas Diffusion Layer
,”
Energy Fuels
,
22
, pp.
1200
1203
.10.1021/ef7007024
17.
Lin
,
J. H.
,
Chen
,
W. H.
,
Su
,
S. H.
,
Liao
,
Y. K.
, and
Ko
,
T. H.
,
2008
, “
Carbon Film Coating on Gas Diffusion Layer for Proton Exchange Membrane Fuel Cells
,”
J. Power Sources
,
84
, pp.
38
43
.10.1016/j.jpowsour.2008.06.040
18.
Kannan
,
M.
,
Cindrella
,
L.
, and
Munukutla
,
L.
,
2008
, “
Functionally Graded Nano-Porous Gas Diffusion Layer for Proton Exchange Membrane Fuel Cells Under Low Relative Humidity Conditions
,”
Electrochim. Acta
,
53
, pp.
2417
2422
.10.1016/j.electacta.2007.10.013
19.
Kannan
,
M.
,
Sadananda
,
S.
,
Munukutla
,
L.
,
Wertz
,
J.
, and
Thommes
,
M.
,
2008
, “
Wire Rod Coating Process of Gas Diffusion Layers Fabrication for Proton Exchange Membrane Fuel Cells
,”
J. Power Sources
,
178
, pp.
231
237
.10.1016/j.jpowsour.2007.12.020
20.
Chen
,
J.
,
Xu
,
H.
,
Zhang
,
H.
, and
Yi
,
B.
,
2008
, “
Facilitating Mass Transport in Gas Diffusion Layer of PEMFC by Fabricating Micro-Porous Layer With Dry Layer Preparation
,”
J. Power Sources
,
182
, pp.
531
539
.10.1016/j.jpowsour.2008.04.031
21.
Ramasamy
,
R. P.
,
Kumbur
,
E. C.
,
Mench
,
M. M.
,
Liu
,
W.
,
Moore
,
D.
, and
Murthy
,
M.
,
2008
, “
Investigation of Macro- and Micro-Porous Layer Interaction in Polymer Electrolyte Fuel Cells
,”
Int. J. Hydrogen Energy
,
33
, pp.
3351
3367
.10.1016/j.ijhydene.2008.03.053
22.
Selvarani
,
G.
,
Sahu
,
A. K.
,
Sridhar
,
P.
,
Pitchumani
,
S.
, and
Shukla
,
A. K.
,
2008
, “
Effect of Diffusion-Layer Porosity on the Performance of Polymer Electrolyte Fuel Cells
,”
J. Appl. Electrochem.
,
38
, pp.
257
362
.10.1007/s10800-007-9448-4
23.
Kundu
,
S.
,
Karan
,
K.
,
Fowler
,
M.
,
Simon
,
L. C.
,
Peppley
,
B.
, and
Halliop
,
E.
,
2008
, “
Influence of Micro-Porous Layer and Operating Conditions on the Fluoride Release Rate and Degradation of PEMFC Membrane Electrode Assemblies
,”
J. Power Sources
,
179
, pp.
693
699
.10.1016/j.jpowsour.2007.11.117
24.
Dai
,
W.
,
Wang
,
H.
,
Yuan
,
X. Z.
,
Martin
,
J.
,
Shen
,
J.
,
Pan
,
Mu.
, and
Luo
,
Z.
,
2009
, “
Measurement of Water Transport Rates Across the Gas Diffusion Layer in a Proton Exchange Membrane Fuel Cell, and the Influence of Polytetrafluoroethylene Content and Micro-Porous Layer
,”
J. Power Sources
,
188
, pp.
122
126
.10.1016/j.jpowsour.2008.11.079
25.
Kitahara
,
T.
,
Konomi
,
T.
, and
Nakajima
,
H.
,
2010
, “
Microporous Layer Coated Gas Diffusion Layers for Enhanced Performance of Polymer Electrolyte Fuel Cells
,”
J. Power Sources
,
195
, pp.
2202
2211
.10.1016/j.jpowsour.2009.10.089
26.
Stampino
,
P. G.
,
Omati
,
L.
, and
Dotelli
,
G.
,
2011
, “
Electrical Performance of PEM Fuel Cells With Different Gas Diffusion Layers
,”
ASME J. Fuel Cell Sci. Technol.
,
8
, p.
041005
.10.1115/1.4003630
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