This work presents electromigration reliability and patterns of Sn–3Ag–0.5Cu and Sn3Ag1.5CuSn3Ag0.5Cu composite flip-chip solder joints with TiNi(V)Cu under bump metallurgy (UBM), bonded on AuNiCu substrate pads. The solder joints were subjected to an average current density of 5kAcm2 under an ambient temperature of 150°C. Under the situation when electron charges flow from the UBM toward the substrate, Sn diffuses from the Cu–Ni–Sn intermetallic compound developed around the UBM toward the UBM and eventually causes the Ni(V) layer to deform. Electromigration reliability of Sn3Ag1.5CuSn3Ag0.5Cu composite flip-chip solder joints was found to be better than that of Sn–3Ag–0.5Cu solder joints. According to the morphological observations on cross-sectioned solder joints, a failure mechanism is proposed as follows. Since the deformation of the Ni(V) layer as a result of Sn diffusion toward the UBM is considered as the dominant failure, a greater Cu weight content in the solder joints would trap more Sn in the Sn–Cu interfacial reaction and would therefore retard the diffusion of Sn toward the UBM and hence enhance the electromigration reliability.

1.
Tu
,
K. N.
, 2003, “
Recent Advances on Electromigration in Very-Large-Scale-Integration of Interconnects
,”
J. Appl. Phys.
0021-8979,
94
(
9
), pp.
5451
5473
.
2.
Yen
,
Y. W.
, and
Chen
,
S. W.
, 2004, “
Phase Equilibria of the Ag-Sn-Cu Ternary System
,”
J. Mater. Res.
0884-2914,
19
(
8
), pp.
2298
2305
.
3.
Tu
,
K. N.
,
Yeh
,
C. C.
,
Liu
,
C. Y.
, and
Chen
,
C.
, 2000, “
Effect of Current Crowding on Vacancy Diffusion and Void Formation in Electromigration
,”
Appl. Phys. Lett.
0003-6951,
76
(
8
), pp.
988
990
.
4.
Yoon
,
J.-W.
,
Kim
,
S.-W.
, and
Jung
,
S.-B.
, 2005, “
Interfacial Reaction and Mechanical Properties of Eutectic Sn‐0.7Cu∕Ni BGA Solder Joints During Isothermal Long-Term Aging
,”
J. Alloys Compd.
0925-8388,
391
(
1–2
), pp.
82
89
.
5.
Lin
,
Y. L.
,
Lai
,
Y.-S.
,
Tsai
,
C. M.
, and
Kao
,
C. R.
, 2006, “
Effect of Surface Finish on the Failure Mechanisms of Flip-Chip Solder Joints Under Electromigration
,”
J. Electron. Mater.
0361-5235,
35
(
12
), pp.
2147
2153
.
6.
Lai
,
Y.-S.
,
Lee
,
C.-W.
,
Chiu
,
Y.-T.
, and
Shao
,
Y.-H.
, 2006, “
Electromigration of 96.5Sn-3Ag-0.5Cu Flip-Chip Solder Bumps Bonded on Substrate Pads of Au∕Ni∕Cu or Cu Metallization
,”
Proceedings of the 56th Electronic Components and Technology Conference
,
San Diego, CA
, pp.
641
645
.
7.
Shao
,
Y.-H.
,
Yang
,
Y.-S.
, and
Lai
,
Y.-S.
, 2006, “
Electromigration of 99.3Sn-0.7Cu∕96.5Sn-3Ag-0.5Cu Composite Flip-Chip Solder Bumps Bonded on Substrate Pads of Au∕Ni∕Cu or Cu Metallization
,”
Proceedings of the 2006 Annual Meeting of the Chinese Society of Materials Science
,
Tainan, Taiwan
, Paper No. P03-172.
8.
Lai
,
Y.-S.
,
Lee
,
C.-W.
, and
Kao
,
C.-L.
, 2007, “
Effect of Test Conditions on Electromigration Reliability of Sn-Ag-Cu Flip-Chip Solder Interconnects
,”
ASME J. Electron. Packag.
1043-7398,
129
(
1
), pp.
56
62
.
9.
Lai
,
Y.-S.
, and
Lee
,
C.-W.
, 2007, “
Electromigration Reliability and Morphologies of 62Sn-36Pb-2Ni and 62Sn-36Pb-2Cu Flip-Chip Solder Joints
,”
IEEE Trans. Compon. Packag. Technol.
1521-3331,
30
(
3
), pp.
526
531
.
10.
Wu
,
J.-D.
,
Zheng
,
P.-J.
,
Lee
,
C.-W.
,
Hung
,
S.-C.
, and
Lee
,
J.-J.
, 2006, “
A Study in Flip-Chip UBM∕Bump Reliability With Effects of SnPb Solder Composition
,”
Microelectron. Reliab.
0026-2714,
46
(
1
), pp.
41
52
.
11.
Lai
,
Y.-S.
, and
Kao
,
C.-L.
, 2006, “
Electrothermal Coupling Analysis of Current Crowding and Joule Heating in Flip-Chip Packages
,”
Microelectron. Reliab.
0026-2714,
46
(
8
), pp.
1357
1368
.
12.
Lai
,
Y.-S.
, and
Kao
,
C.-L.
, 2006, “
Calibration of Electromigration Reliability of Flip-Chip Packages by Electrothermal Coupling Analysis
,”
J. Electron. Mater.
0361-5235,
35
(
5
), pp.
972
977
.
13.
Ye
,
H.
,
Basaran
,
C.
, and
Hopkins
,
D. C.
, 2003, “
Thermomigration in Pb-Sn Solder Joints Under Joule Heating During Electric Current Stressing
,”
Appl. Phys. Lett.
0003-6951,
82
(
7
), pp.
1045
1047
.
14.
Huang
,
A. T.
,
Gusak
,
A. M.
,
Tu
,
K. N.
, and
Lai
,
Y.-S.
, 2006, “
Thermomigration in SnPb Composite Flip Chip Solder Joints
,”
Appl. Phys. Lett.
0003-6951,
88
, p.
141911
.
15.
Huang
,
A. T.
,
Tu
,
K. N.
, and
Lai
,
Y.-S.
, 2006, “
Effect of the Combination of Electromigration and Thermomigration on Phase Migration and Partial Melting in Flip Chip Composite SnPb Solder Joints
,”
J. Appl. Phys.
0021-8979,
100
, p.
033512
.
16.
Ouyang
,
F.-Y.
,
Tu
,
K. N.
,
Lai
,
Y.-S.
, and
Gusak
,
A. M.
, 2006, “
Effect of Entropy Production on Microstructure Change in Eutectic SnPb Flip Chip Solder Joints by Thermomigration
,”
Appl. Phys. Lett.
0003-6951,
89
, p.
221906
.
17.
Lai
,
Y.-S.
, and
Kao
,
C.-L.
, 2006, “
Characteristics of Current Crowding in Flip-Chip Solder Bumps
,”
Microelectron. Reliab.
0026-2714,
46
(
5–6
), pp.
915
922
.
18.
Tsai
,
C. M.
,
Lin
,
Y. L.
,
Tsai
,
J. Y.
,
Lai
,
Y.-S.
, and
Kao
,
C. R.
, 2006, “
Local Melting Induced by Electromigration in Flip-Chip Solder Joints
,”
J. Electron. Mater.
0361-5235,
35
(
5
), pp.
1005
1009
.
19.
Ouyang
,
F.-Y.
,
Tu
,
K. N.
,
Kao
,
C.-L.
, and
Lai
,
Y.-S.
, 2007, “
Effect of Electromigration in the Anodic Al Interconnect on Melting of Flip Chip Solder Joints
,”
Appl. Phys. Lett.
0003-6951,
90
, p.
211914
.
20.
Liu
,
Y.-H.
, and
Lin
,
K.-L.
, 2005, “
Damages and Microstructural Variation of High-Lead and Eutectic SnPb Composite Flip Chip Solder Bumps Induced by Electromigration
,”
J. Mater. Res.
0884-2914,
20
(
8
), pp.
2184
2193
.
21.
Hsu
,
Y.-C.
,
Chou
,
C.-K.
,
Liu
,
P.-C.
,
Chen
,
C.
,
Yao
,
D. J.
,
Chou
,
T.
. and
Tu
,
K. N.
, 2005, “
Electromigration in Pb-Free SnAg3.8Cu0.7 Solder Stripes
,”
J. Appl. Phys.
0021-8979,
98
, p.
033523
.
You do not currently have access to this content.