In earlier publications, heat Q← is defined as an interaction that is entirely distinguishable from work W→. The energy exchanged Q← is TQ times the entropy exchanged S←, where TQ is the almost common temperature of the interacting systems. Here, we define diffusion as another interaction that is entirely distinguishable from both work and heat, and that involves exchanges of energy, entropy, and amount of a constituent. It is an interaction between two systems A and B that pass through stable equilibrium states while their respective parameters remain fixed, and that have almost equal temperatures TA ≈ TB ≈ TD and almost equal total potentials μA ≈ μB ≈ μD of the diffusing constituent. The exchanges of entropy S→, energy E→, and amount of constituent n→ out of one system satisfy the relation S→ = (E→ −μDn→)/TD. In the limit of n→ = 0, a diffusion interaction becomes heat.
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June 1994
Research Papers
What is Diffusion?
E. P. Gyftopoulos,
E. P. Gyftopoulos
Mechanical Engineering Department, Massachusetts Institute of Technology, Cambridge, MA 02139
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M. I. Flik,
M. I. Flik
Mechanical Engineering Department, Massachusetts Institute of Technology, Cambridge, MA 02139
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G. P. Beretta
G. P. Beretta
Universita` di Brescia, Brescia, Italy
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E. P. Gyftopoulos
Mechanical Engineering Department, Massachusetts Institute of Technology, Cambridge, MA 02139
M. I. Flik
Mechanical Engineering Department, Massachusetts Institute of Technology, Cambridge, MA 02139
G. P. Beretta
Universita` di Brescia, Brescia, Italy
J. Energy Resour. Technol. Jun 1994, 116(2): 136-139 (4 pages)
Published Online: June 1, 1994
Article history
Received:
August 6, 1992
Revised:
August 30, 1993
Online:
April 16, 2008
Citation
Gyftopoulos, E. P., Flik, M. I., and Beretta, G. P. (June 1, 1994). "What is Diffusion?." ASME. J. Energy Resour. Technol. June 1994; 116(2): 136–139. https://doi.org/10.1115/1.2906018
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