A study of the effects of nitric oxide (NO) models on the prediction of NO formation in a gas-fired regenerative furnace with highly preheated air was undertaken. Three chemical kinetic processes for NO formation/depletion, i.e., thermal NO, prompt NO, and NO reburning, are included. In the thermal NO model, the sensitivity encountered when using two different approaches, namely the equilibrium approach and the partial equilibrium approach, for determining the O radical concentration was studied. The effects of the third reaction in the thermal NO mechanism, NO reduction (reburning) mechanism, and different types of probability density functions (PDFs) on the NO predictions have also been tested. The sensitivity of the excess air ratio on the NO generation rate in the furnace has been investigated. Finally, the impact of the temperature on the NO formation rate in the regenerative furnace was discussed. [S0195-0738(00)00304-6]

1.
Chen
,
J.
, and
Kollmann
,
W.
,
1992
, “
PDF Modeling and Analysis of Thermal NO Formation in Turbulent Nonpremixed Hydrogen-Air Jet Flames
,”
Combust. Flame
,
88
, pp.
397
412
.
2.
Glarborg, P., Lilleheie, N. I., Byggstoyl, S., Magnussen, B. F., Kilpinen, P., and Hupa, M., 1992, “A Reduced Mechanism for Nitrogen Chemistry in Methane Combustion,” Proc., 24th Symposium (International) on Combustion, The Combustion Institute, pp. 889–898.
3.
Boardman
,
R. D.
,
Eatough
,
C. N.
,
Germane
,
G. J.
, and
Smoot
,
L. D.
,
1993
, “
Comparison of Measurements and Predictions of Flame Structure and Thermal NOx in a Swirling, Natural Gas Diffusion Flame
,”
Combust. Sci. Technol.
,
93
, pp.
193
210
.
4.
Kenbar
,
A. M. A.
,
Beltagui
,
S. A.
,
Ralston
,
T.
, and
Maccallum
,
N. R. L.
,
1993
, “
Measurement and Modelling of NOx Formation in a Gas Fired Furnace
,”
Combust. Sci. Technol.
,
93
, pp.
173
192
.
5.
Chen
,
C.
,
Chang
,
K.
, and
Chen
,
J.
,
1994
, “
Application of a Robust β-pdf Treatment to Analysis of Thermal NO Formation in Nonpremixed Hydrogen-Air Flame
,”
Combust. Flame
,
98
, pp.
375
390
.
6.
Ishii
,
T.
,
Zhang
,
C.
, and
Sugiyama
,
S.
,
1998
, “
Numerical Simulations of Highly Reheated Air Combustion in an Industrial Furnace
,”
ASME J. Energy Resour. Technol.
,
120
, pp.
276
284
.
7.
Peters
,
A. A. F.
, and
Weber
,
R.
,
1995
, “
Mathematical Modeling of a 2.25 MWt Swirling Natural Gas Flame. Part 1: Eddy Break-up Concept for Turbulent Combustion; Probability Density Function Approach for Nitric Oxide Formation
,”
Combust. Sci. Technol.
,
110–111
, pp.
67
101
.
8.
Hanson, R. K., and Salimian, S., 1984, “Survey of Rate Constants in H/N/O System,” Combustion Chemistry, ed., W. C. Gardiner, Springer-Verlag, New York, NY.
9.
Kent, J. H., and Bilger, R. W., 1977, “The Prediction of Turbulent Diffusion Flame Fields and Nitric Oxide Formation,” Proc., 16th Symposium (International) on Combustion, The Combustion Institute, pp. 1643–1656.
10.
Westenberg
,
A. A.
,
1971
, “
Kinetics of NO and CO in Lean, Premixed Hydrocarbon-Air Flames
,”
Combust. Sci. Technol.
,
4
, p.
59
59
.
11.
Warnatz, J., 1991, “NOx Formation in High Temperature Processes,” Proc., European Gas Conference, pp. 303–320.
12.
De Soete, G. G., 1975, “Overall Reaction Rates of NO and N2 Formation from Fuel Nitrogen,” Proc., 15th Symposium (International) on Combustion, The Combustion Institute, pp. 1093–1102.
13.
Dupont
,
V.
,
Porkashanian
,
M.
,
Williams
,
A.
, and
Woolley
,
R.
,
1993
, “
Reduction of NOx Formation in Natural Gas Burner Flames
,”
Fuel
,
72
, No.
4
, pp.
497
503
.
14.
Bowman, C. T., 1991, “Chemistry of Gaseous Pollutant Formation and Destruction,” Fossil Fuel Combustion—A Source Book, eds., W. Bartok, W. and A. F. Sarofim, Wiley, New York, NY.
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