Integrated gasification combined cycles (IGCC) exhibit conditions particularly favourable to the sequestration of CO2. The concept pursued in this paper is the generation of syngas low in carbon, where most of the heating value of the coal fuel is carried by hydrogen. Catalytic shift reactors convert most of the CO in the syngas into CO2, which is subsequently removed by physical absorption and then compressed to make it suitable for transport and permanent storage. Energy balances, performance, and cost of electricity are evaluated for two plants based on a Texaco gasifier and a large, heavy-duty gas turbine giving an overall IGCC power output between 350 and 400 MW. In one plant, the raw syngas exiting the gasifier is cooled in a high-temperature, radiative cooler; in the other it is quenched by the injection of liquid water. With respect to “conventional” Texaco IGCCs, the reduction of specific CO2 emissions by 90 percent reduces LHV efficiency from 5 to 7 percentage points and increases the cost of electricity of about 40 percent. These penalties can be reduced by accepting lower reductions of CO2 emissions. Compared to the semiclosed cycle considered by other authors, where CO2 is the main component of the gas turbine working fluid, the plants analyzed here exhibit higher efficiency over the whole range of specific CO2 emissions.
1.
ASPEN PLUS release 9.3, Reference Manual—Volume 2, 1996, “Physical Property Methods and Models,” Aspen Technology Inc., Cambridge, MA.
2.
Black, C. R., McDaniel, J. E., 1996, “Polk Power Station IGCC Projects,” Proc. of “Gasification Technologies Conference,” San Francisco, CA.
3.
Blok
K.
Williams
R. H.
Katofski
R. E.
Hendricks
C. A.
1997
, “Hydrogen Production from Natural Gas, Sequestration of Recovered CO2 in Depleted Gas Wells and Enhanced Natural Gas Recovery
,” Energy
, Vol. 22
, pp. 161
–168
.4.
Bucklin
R. W.
Schendel
R. L.
1984
, “Comparison of Fluor Solvent and Selexol Processes
,” Energy Progress
, Vol. 4
, No. 3
, pp. 137
–142
.5.
The Capture, Utilization and Disposal of Carbon Dioxide from Fossil Fuel-Fired Power Plants, 1993 report prepared for U.S. Dep. of Energy, contract No. DE-FG02-92ER30194. A000, July 1993.
6.
Chiesa, P., Consonni, S., Lozza, G., and Macchi, E., 1993, “Predicting the Ultimate Performance of Advanced Power Cycles Based on Very High Temperature Gas Turbine Engines,” ASME Paper 93-GT-223.
7.
Chiesa, P., and Lozza, G., 1998, “CO2 Emission Abatement in IGCC Power Plant by Semiclosed Cycles. Part A: With Oxygen-Blown Combustion,” ASME paper 98-GT-384.
8.
Consonni, S., 1992, “Performance Prediction of Gas/Steam Cycles for Power Generation,” Ph.D. thesis No. 1893-T, Mechanical and Aerospace Engineering Dept., Princeton University, Princeton, NJ.
9.
Consonni, S., Larson, E., Kreutz, T. and Berglin N., 1997, “Black Liquor-Gasifier/Gas Turbine Cogeneration,” ASME Paper 97-GT-273.
10.
Echt, W. I., 1998, personal communication, Union Carbide Corporation Danbury, CT.
11.
Feron
P. H. M.
Jansen
A. E.
Klaassen
R.
1992
, “Membrane Technology in Carbon Dioxide Removal
,” Energy Convers. Mgmt.
, Vol. 33
, No. 5–8
, pp. 421
–428
.12.
Freund
P.
Ormerod
W. G.
1997
, “Progress Toward Storage of Carbon Dioxide
,” Energy Convers. Mgmt.
, Vol. 38
, Suppl., pp. S199–S204
S199–S204
.13.
Fujioka
Y.
1997
, “Cost Comparison in Various CO2 Ocean Disposal Options
,” Energy Convers. Mgmt.
, Vol. 38
, Suppl., pp. S273–S277
S273–S277
.14.
Go¨ttlicher
G. g.
Pruscheck
R.
1996
, “Comparison of CO2 Removal Systems for Fossil-Fuelled Power Plant Processes
,” Energy Convers, Mgmt.
, Vol. 38
, Suppl., pp. S173–S178
S173–S178
.15.
Hagerdon, G., and Paul, I., 1997, “Innovative Steam Power Plant Technology: New Solution for the Benefit of Customer Worldwide,” Proceedings, Power-Gen Europe ’97, Madrid, Spain, June 1997., Vol. III, PennWell, Utrecht, The Netherlands, pp. 383–404.
16.
Ha¨user, U., and Herzog, M., 1997, “Design Data of Steam Power Plants: An Economic and Environmental Evaluation,” Proceedings, Power-Gen Europe ’97, Vol. III, PennWell, Utrecht, The Netherlands, pp. 335–357.
17.
Hendriks, C., 1994, “Carbon Dioxide Removal from Coal-Fired Power Plants,” Ph.D. thesis, University of Utrecht, The Netherlands.
18.
Holloway
S.
1997
, “An Overview of the Underground Disposal of Carbon Dioxide
,” Energy Convers. Mgmt.
, Vol. 38
, Suppl., pp. S193–S198
S193–S198
.19.
Hough, M. F., Kelty, F. J., O’Keefe, L. F., Thone, P. W., and Weissman, R. C. (1997), “The Bottomless Refinery: Gasification as The Optimum Solution to Maximum Refinery,” presented at the Gasification Technology in Practice, February 26-27, 1997, Milan, Italy.
20.
Houghton, J. T., Jenkins, G. J., and Ephraums, J. J., eds., 1990, Climate Change: The IPCC Scientific Assessment, Cambridge University Press, Cambridge, UK.
21.
Johansson
T. B.
Williams
R. H.
Ishitani
H.
Edmonds
J. A.
1996
, “Options for Reducing CO2 Emissions for the Energy Supply Sector
,” Energy Policy
, Vol. 24
, pp. 985
–1003
.22.
Kohl, A., and Riesenfeld, F., 1985, Gas Purification, 4th ed., Gulf Publishing Company, Houston, TX.
23.
Kubek, D. J., Polla, E., and Wilcher, F. P., 1997, “Purification and Recovery Options for Gasification,” Proceedings, Gasification Technology in Practice, Gulf Publishing Company, Houston, TX.
24.
Larson, E., and Consonni, S., 1997, “Performance of Black Liquor Gasifier/Gas Turbine Combined Cycle Cogeneration in the Kraft Pulp and Paper Industry,” Proceedings, 3rd Biomass Conference of the Americas, Montreal, Canada, Pergamon-Elsevier Science, New York.
25.
Lozza, G., 1990, “Bottoming Steam Cycles for Combined Gas-Steam Power Plants: A Theoretical Estimation of Steam Turbine Performance and Cycle Analysis,” Proceedings, 1990 ASME Cogen-Turbo, ASME, New York, pp. 83–92.
26.
Macchi
E.
Consonni
S.
Lozza
G.
Chiesa
P.
1995
, “An Assessment of the Thermodynamic Performance of Mixed Gas-Steam Cycles—Part A: Intercooled and Steam-Injected Cycles
,” ASME JOURNAL OF ENGINEERING FOR GAS TURBINES AND POWER
, Vol. 117
, pp. 489
–498
.27.
Mathieu, P., De Ruick, J., 1993, “CO2 Capture in CC and IGCC Power Plants Using a CO2 Gas Turbine,” Proceedings, IGTI Cogen-Turbo Congress, ASME, New York, pp. 77–84.
28.
McMullan, J. T., et al., 1995, “Techno-Economic Assessment Studies of Fossil Fuels and Fuel Woods Power Generation Technologies,” Joule II Programme, R&D in Clean Coal Technology, report to the European Commission, Brussels, Belgium, CIEMAT, Madrid, Spain.
29.
Schu¨tz
M.
Daun
M.
Weinspach
P. M.
Krumbeck
M.
Hein
K. R. G.
1992
, “Study on the CO2 Recovery from an IGCC Plant
,” Energy Convers. Mgmt.
, Vol. 33
, No. 5–8
, pp. 357
–363
.30.
Smelser, S. C., Stock, R. M., McCleary, G. J., 1991, “Engineering and Economic Evaluation of CO2 Removal from Fossil-Fuel-Fired Power Plant,” EPRI Report IE-7365, Palo Alto, CA.
31.
Socolow, R. H., ed., 1997, “Fuels Decarbonization and Carbon Sequestration: Report of a Workshop,” PU/CEES Report No. 302, Princeton University, Princeton, NJ.
32.
Storgaard, L., 1997, personal communication, Haldor Topsoe, Lyngby, Denmark.
33.
Stull, D. R., and Prophet, H., project directors, 1971, JANAF Thermochemical Tables, 2nd ed., U.S. National Bureau of Standards, Washington D.C.
34.
TAG—Technical Assessment Guide (electric supply), 1993 EPRI Report TR-102275 Vol. 1, Rev. 7, Palo Alto, CA.
35.
Todd, D. M., and Stoll, H., 1997, “Integrated Gasification Combined Cycle—The Preferred Power Technology of a Variety of Applications,” Proceedings, Power-Gen Europe ’97, Vol. III, PennWell, Utrecht, The Netherlands, pp. 365–384.
36.
Treybal, 1980, Mass-Transfer Operations, Mc-Graw-Hill, New York.
37.
Turkemburg
W.
1997
, “Sustainable Development, Climate Change and Carbon Dioxide Removal (CDR)
,” Energy Convers. Mgmt.
, Vol. 38
, Suppl., pp. S3–S12
S3–S12
.38.
Ulizar, I., and Pilidis, P., 1997, “Design of a Semiclosed Cycle Gas Turbine with Carbon Dioxide-Argon as Working Fluid,” ASME Paper 97-GT-125.
39.
Van der Sluijs
J. P.
Hendricks
C. A.
Blok
K.
1992
, “Feasibility of Polymer Membranes for Carbon Dioxide Recovery from Flue Gas
,” Energy Convers. Mgmt.
, Vol. 33
, No. 5–8
, pp. 429
–436
.40.
Weiss, M. M., 1997, “Selection of the Acid Gas Removal Process for IGCC Applications,” Proceedings, Gasification Technology in Practice.
41.
West, S. S., and Ereaut, P. R., 1997, “Air-Blown or Oxygen Blown Gasification for Power Generation?” Proceedings, Gasification Technology in Practice.
42.
Wondergem, A., 1997, “Selection of Gas Turbine(s) for a 110 MW Power Station,” Proceedings, Power-Gen Europe ’97, Vol. III, PennWell, Utrecht, The Netherlands, pp. 47–55.
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