A novel and inexpensive bucky gel electrode was investigated for use as the electrode substrate for polypyrrole deposition. Potentiostatic deposition of polypyrrole onto gold and bucky gel electrodes was carried out at +1.2 V versus saturated calomel electrode for 1 h in a standard three-electrode electrochemical cell. The electroactive polypyrrole membrane was successfully deposited onto bucky gel, and its surface morphology studied using scanning electron microscopy. Given the bucky gel’s dual ability to both conduct electricity and ions, this work establishes the first step toward a semisolid ion-gating system to be used in further applications.
Issue Section:
Technical Briefs
Keywords:
bioelectric phenomena,
biomembrane transport,
biomimetics,
cellular biophysics,
electrochemical electrodes,
electrodeposition,
fullerenes,
gels,
organic compounds,
scanning electron microscopy,
surface morphology,
biomimicry,
electroactive polymers,
polypyrrole,
bucky gel,
artificial cell membrane
References
1.
Sands
, Z.
, Grottesi
, A.
, and Sansom
, M. S.
, 2005, “Voltage-Gated Ion Channels
,” Curr. Biol.
, 15
(2
), pp. R44
–R47
.2.
Fukushima
, T.
, Asaka
, K.
, Kosaka
, A.
, and Aida
, T.
, 2005, “Fully Plastic Actuator Through Layer-by-Layer Casting With Ionic-Liquid-Based Bucky Gel
,” Angew. Chem., Int. Ed.
, 44
(16
), pp. 2410
–2413
.3.
Fukushima
, T.
, and Aida
, T.
, 2007, ““Ionic Liquids for Soft Functional Materials With Carbon nanotubes”
,” Chem.-Eur. J.
, 13
(18
), pp. 5048
–5058
.4.
Takeuchi
, I.
, Asaka
, K.
, Kiyohara
, K.
, Sugino
, T.
, Terasawa
, N.
, Mukai
, K.
, Fukushima
, T.
, and Aida
, T.
, 2009, “Electromechanical Behavior of Fully Plastic Actuators Based on Bucky Gel Containing Various Internal Ionic Liquids
,” Electrochim. Acta.
, 54
(6
), pp. 1762
–1768
.5.
Katakabe
, T.
, Kaneko
, T.
, Watanabe
, M.
, Fukushima
, T.
, and Aida
, T.
, 2005, “Electric Double-Layer Capacitors Using “Bucky gels” Consisting of an Ionic Liquid and Carbon Nanotubes
,” J. Electrochem. Soc.
, 152
(10
), pp. A1913
–A1916
.6.
Kamamichi
, N.
, Yamakita
, M.
, Asaka
, M.
, Zhi-Wei
, K.
, and Mukai
, T. L.
, 2007, “Sensor Property of a Novel EAP Device With Ionic-Liquid-Based Bucky Gel
,” IEEE Sensors 2007
, pp. 221
–224
.7.
Zhou
, D.
, Too
, C. O.
, Wallace
, G. G.
, Hodges
, A. M.
, and Mau
, A. W. H.
, 2000, “Protein Transport and Separation Using Polypyrrole Coated, Platinised Polyvinylidene Fluoride Membranes
,” React. Funct. Polym.
, 45
(3
), pp. 217
–226
.8.
Zine
, N.
, Bausells
, J.
, Vocanson
, F.
, Lamartine
, R.
, Asfari
, Z.
, Teixidor
, F.
, Crespo
, E.
, de Oliveira
, I. M.
, Samitier
, J.
, and Errachid
, A.
, 2006, “Potassium-Ion Selective Solid Contact Microelectrode Based on a Novel 1,3-(di-4-oxabutanol)- calix[4]arene-crown-5 Neutral Carrier
,” Electrochim. Acta
, 51
(24
), pp. 5075
–5079
.9.
Gandhi
, M. R.
, Murray
, P.
, Spinks
, G. M.
, and Wallace
, G. G.
, 1995, “Mechanism of Electromechanical Actuation in Polypyrrole
,” Synth. Met.
, 73
(3
), pp. 247
–256
.10.
Jurewicz
, K.
, Delpeux
, S.
, Bertagna
, V.
, Bguin
, F.
, and Frackowiak
, E.
, 2001, “Supercapacitors From Nanotubes/Polypyrrole Composites
,” Chem. Phys. Lett.
, 347
(1–3
), pp. 36
–40
.11.
Wang
, J.
, Too
, C.
, Zhou
, D.
, and Wallace
, G.
, 2005, ““Novel Electrode Substrates for Rechargeable Lithium/Polypyrrole Batteries
,” J. Power Sources
, 140
(1
), pp. 162
–167
.12.
Partridge
, A. C.
, Milestone
, C. B.
, Too
, C. O.
, and Wallace
, G. G.
, 1999, “Polypyrrole Based Cation Transport membranes
,” J. Membr. Sci.
, 152
(1
), pp. 61
–70
.Copyright © 2011
by American Society of Mechanical Engineers
You do not currently have access to this content.