The present study investigates the feasibility, efficiency, and system design of a hybrid solar system generating electric power for stationary applications such as residential buildings. The system is fed by methanol and combines methanol steam reforming and proton exchange membrane (PEM) fuel cells with solar collectors to generate the required heat for the steam reforming. The synergies of these technologies lead to a highly efficient system with significantly larger power densities compared to conventional systems and generate tremendous advantages in terms of installation and operation costs. The present investigation describes the entire proposed system and its components and presents first analytical, numerical, and experimental results of a larger project to prove the feasibility of such a system by analyzing first a bench test demonstrator generating around 10 W of electric power and finally a prototype for an entire single-family household. It is shown that the methanol-to-electricity efficiency of the entire system is above 50%.
Issue Section:
Research Papers
Keywords:
biomass,
chemistry,
collector,
efficiency,
energy,
exergy,
fluid flow,
fuel,
hydrogen,
renewable,
solar reactor,
system,
thermal power,
thermodynamics
References
1.
Aartun
, I.
, Silberova
, B.
, Venvik
, H.
, Pfeifer
, P.
, Gorke
, O.
, Schubert
, K.
, and Holmen
, A.
, 2005
, “Hydrogen Production From Propane in Rh-Impregnated Metallic Microchannel Reactors and Alumina Foams
,” Catal. Today
, 105
(3–4
), pp. 469
–478
.10.1016/j.cattod.2005.06.0252.
Bieberle-Huetter
, A.
, Beckel
, D.
, Infortuna
, A.
, Muecke
, U.
, Rupp
, J.
, Gauckler
, L.
, Rey-Mermet
, S.
, Muralt
, P.
, Bieri
, N.
, Hotz
, N.
, Stutz
, M. J.
, Poulikakos
, D.
, Heeb
, P.
, Mueller
, P.
, Bernard
, A.
, Gmuer
, R.
, and Hocker
, T.
, 2008
, “A Micro-Solid Oxide Fuel Cell System as Battery Replacement
,” J. Power Sources
, 177
(1
), pp. 123
–130
.10.1016/j.jpowsour.2007.10.0923.
Chaniotis
, A.
, and Poulikakos
, D.
, 2005
, “Modeling and Optimization of Catalytic Partial Oxidation Methane Reforming for Fuel Cells
,” J. Power Sources
, 142
(1–2
), pp. 184
–193
.10.1016/j.jpowsour.2004.10.0184.
Hickman
, D.
, and Schmidt
, L.
, 1993
, “Production of Syngas by Direct Catalytic-Oxidation of Methane
,” Science
, 259
(5093
), pp. 343
–346
.10.1126/science.259.5093.3435.
Hotz
, N.
, Stutz
, M. J.
, Loher
, S.
, Stark
, W.
, and Poulikakos
, D.
, 2007
, “Syngas Production From Butane Using a Flame-Made Rh/Ce0.5Zr0.5O2 Catalyst
,” Appl. Catal.
, B, 73
(3–4
), pp. 336
–344
.10.1016/j.apcatb.2007.01.0016.
Laosiripojana
, N.
, and Assabumrungrat
, S.
, 2006
, “Hydrogen Production From Steam and Autothermal Reforming of LPG Over High Surface Area Ceria
,” J. Power Sources
, 158
(2
), pp. 1348
–1357
.10.1016/j.jpowsour.2005.10.0587.
Silberova
, B.
, Venvik
, H.
, Walmsley
, J.
, Holmen
, A.
, 2005
, “Small-Scale Hydrogen Production From Propane
,” Catal. Today
, 100
(3–4
), pp. 457
–462
.10.1016/j.cattod.2004.09.0788.
Amphlett
, J. C.
, Creber
, K. A. M.
, Davis
, J. M.
, Mann
, R. F.
, Peppley
, B. A.
, and Stokes
, D. M.
, 1994
, “Hydrogen-Production by Steam Reforming of Methanol for Polymer Electrolyte Fuel-Cells
,” Int. J. Hydrogen Energy
, 19
(2
), pp. 131
–137
.10.1016/0360-3199(94)90117-19.
Kundu
, A.
, Jang
, J.
, Lee
, H.
, Kim
, S.
, Gil
, J.
, Jung
, C.
, and Oh
, Y.
, 2006
, “MEMS-Based Micro-Fuel Processor for Application in a Cell Phone
,” J. Power Sources
, 162
(1
), pp. 572
–578
.10.1016/j.jpowsour.2006.06.07510.
Lee
, M. T.
, Greif
, R.
, Grigoropoulos
, C. P.
, Park
, H. G.
, and Hsu
, F. K.
, 2007
, “Transport in Packed-Bed and Wall-Coated Steam-Methanol Reformers
,” J. Power Sources
, 166
(1
), pp. 194
–201
.10.1016/j.jpowsour.2007.01.00711.
Lee
, M. T.
, Hwang
, D. J.
, Greif
, R.
, and Grigoropoulos
, C. P.
, 2009
, “Nanocatalyst Fabrication and the Production of Hydrogen by Using Photon Energy
,” Int. J. Hydrogen Energy
, 34
(4
), pp. 1835
–1843
.10.1016/j.ijhydene.2008.12.02212.
Liguras
, D.
, Goundani
, K.
, and Verykios
, X.
, 2004
, “Production of Hydrogen for Fuel Cells by Catalytic Partial Oxidation of Ethanol Over Structured Ni Catalysts
,” J. Power Sources
, 130
(1–2
), pp. 30
–37
.10.1016/j.jpowsour.2003.12.00813.
Pattekar
, A.
, and Kothare
, M.
, 2005
, “A Radial Microfluidic Fuel Processor
,” J. Power Sources
, 147
(1–2
), pp. 116
–127
.10.1016/j.jpowsour.2005.01.02414.
Suh
, J. S.
, Lee
, M. T.
, Greif
, R.
, and Grigoropoulos
, C. P.
, 2007
, “A Study of Steam Methanol Reforming in a Microreactor
,” J. Power Sources
, 173
(1
), pp. 458
–466
.10.1016/j.jpowsour.2007.04.03815.
Hotz
, N.
, Lee
, M. T.
, Grigoropoulos
, C. P.
, Senn
, S. M.
, and Poulikakos
, D.
, 2006
, “Exergetic Analysis of Fuel Cell Micropowerplants Fed by Methanol
,” Int. J. Heat Mass Transfer
, 49
(15–16
), pp. 2397
–2411
.10.1016/j.ijheatmasstransfer.2006.03.00716.
Yilanci
, A.
, Dincer
, I.
, and Ozturk
, H. K.
, 2008
, “Performance Analysis of a PEM Fuel Cell Unit in a Solar-Hydrogen System
,” Int. J. Hydrogen Energy
, 33
(24
), pp. 7538
–7552
.10.1016/j.ijhydene.2008.10.01617.
Granovskii
, M.
, Dincer
, I.
, and Rosen
, M. A.
, 2008
, “Exergy Analysis of a Gas Turbine Cycle With Steam Generation for Methane Conversion Within Solid Oxide Fuel Cells
,” J. Fuel Cell Sci. Technol.
, 5(3)
, p. 031005
.10.1115/1.289446918.
Obara
, S.
, and Tanno
, I.
, 2008
, “Exergy Analysis of a Regional-Distributed PEM Fuel Cell System
,” Int. J. Hydrogen Energy
, 33
(9
), pp. 2300
–2310
.10.1016/j.ijhydene.2008.02.03619.
Janardhanan
, V. M.
, Heuveline
, V.
, and Deutschmann
, O.
, 2007
, “Performance Analysis of a SOFC Under Direct Internal Reforming Conditions
,” J. Power Sources
, 172
(1
), pp. 296
–307
.10.1016/j.jpowsour.2007.07.00820.
Hotz
, N.
, Senn
, S. M.
, and Poulikakos
, D.
, 2006
, “Exergy Analysis of a Solid Oxide Fuel Cell Micropowerplant
,” J. Power Sources
, 158
(1
), pp. 333
–347
.10.1016/j.jpowsour.2005.09.02321.
Farhad
, S.
, and Hamdullahpur
, F.
, 2009
, “Developing Fuel Map to Predict the Effect of Fuel Composition on the Maximum Efficiency of Solid Oxide Fuel Cells
,” J. Power Sources
, 193
(2
), pp. 632
–638
.10.1016/j.jpowsour.2009.03.05422.
Vargas
, J. V. C.
, and Bejan
, A.
, 2004
, “Thermodynamic Optimization of Internal Structure in a Fuel Cell
,” Int. J. Energy Res.
, 28
(4
), pp. 319
–339
.10.1002/er.96723.
Mitchell
, R. E.
, Gur
, T. M.
, and Lee
, A. C.
, 2009
, “Thermodynamic Analysis of Gasification-Driven Direct Carbon Fuel Cells
,” J. Power Sources
, 194
(2
), pp. 774
–785
.10.1016/j.jpowsour.2009.05.03924.
Rashidi
, R.
, Dincer
, I.
, Naterer
, G. F.
, and Berg
, P.
, 2009
, “Performance Evaluation of Direct Methanol Fuel Cells for Portable Applications
,” J. Power Sources
, 187
(2
), pp. 509
–516
.10.1016/j.jpowsour.2008.11.04425.
Toonssen
, R.
, Woudstra
, N.
, and Verkooijen
, A. H. M.
, 2009
, “Decentralized Generation of Electricity From Biomass With Proton Exchange Membrane Fuel Cell
,” J. Power Sources
, 194
(1
), pp. 456
–466
.10.1016/j.jpowsour.2009.05.04426.
Ameri
, M.
, Ahmadi
, P.
, and Hamidi
, A.
, 2009
, “Energy, Exergy and Exergoeconomic Analysis of a Steam Power Plant: A Case Study
,” Int. J. Energy Res.
, 33
(5
), pp. 499
–512
.10.1002/er.149527.
Dincer
, I.
, Kanoglu
, M.
, and Rosen
, M. A.
, 2007
, “Understanding Energy and Exergy Efficiencies for Improved Energy Management in Power Plants
,” Energy Policy
, 35
(7
), pp. 3967
–3978
.10.1016/j.enpol.2007.01.01528.
Gnanapragasam
, N. V.
, Reddy
, B. V.
, and Rosen
, M. A.
, 2009
, “Optimum Conditions for a Natural Gas Combined Cycle Power Generation System Based on Available Oxygen When Using Biomass as Supplementary Fuel
,” Energy
, 34
(6
), pp. 816
–826
.10.1016/j.energy.2009.03.00629.
Kanoglu
, M.
, and Dincer
, I.
, 2009
, “Performance Assessment of Cogeneration Plants
,” Energy Convers. Manage.
, 50
(1
), pp. 76
–81
.10.1016/j.enconman.2008.08.02930.
Khaliq
, A.
, and Choudhary
, K.
, 2009
, “Exergy Analysis of the Regenerative Gas Turbine Cycle Using Absorption Inlet Cooling and Evaporative Aftercooling
,” J. Energy Inst.
, 82
(3
), pp. 159
–167
.10.1179/014426009X1244816855026231.
Calise
, F.
, Palombo
, A.
, and Vanoli
, L.
, 2006
, “Design and Partial Load Exergy Analysis of Hybrid SOFC-GT Power Plant
,” J. Power Sources
, 158
(1
), pp. 225
–244
.10.1016/j.jpowsour.2005.07.08832.
Haseli
, Y.
, Dincer
, I.
, and Naterer
, G. F.
, 2008
, “Thermodynamic Modeling of a Gas Turbine Cycle Combined With a Solid Oxide Fuel Cell
,” Int. J. Hydrogen Energy
, 33
(20
), pp. 5811
–5822
.10.1016/j.ijhydene.2008.05.03633.
Rashidi
, R.
, Berg
, P.
, and Dincer
, I.
, 2009
, “Performance Investigation of a Combined MCFC System
,” Int. J. Hydrogen Energy
, 34
(10
), pp. 4395
–4405
.10.1016/j.ijhydene.2009.03.03834.
Joshi
, A. S.
, Dincer
, I.
, and Reddy
, B. V.
, 2009
, “Performance Analysis of Photovoltaic Systems: A Review
,” Renewable Sustainable Energy Rev.
, 13
(8
), pp. 1884
–1897
.10.1016/j.rser.2009.01.00935.
Joshi
, A. S.
, Dincer
, I.
, and Reddy
, B. V.
, 2009
, “Thermodynamic Assessment of Photovoltaic Systems
,” Sol. Energy
, 83
(8
), pp. 1139
–1149
.10.1016/j.solener.2009.01.01136.
Kumar
, S.
, and Tiwari
, G. N.
, 2009
, “Thermal Modelling, Validation and Exergetic Analysis of a Hybrid Photovoltaic/Thermal (PV/T) Active Solar Still
,” Int. J. Exergy
, 6
(4
), pp. 567
–591
.10.1504/IJEX.2009.02667837.
Tiwari
, A.
, Sandhu
, G. S.
, Barnwal
, P.
, and Sodha
, M. S.
, 2009
, “Energy and Exergy Metrics Analyses of Hybrid Photovoltaic-Thermal Air Collector
,” Int. J. Exergy
, 6
(5
), pp. 729
–748
.10.1504/IJEX.2009.02749938.
Erek
, A.
, and Dincer
, I.
, 2009
, “A New Approach to Energy and Exergy Analyses of Latent Heat Storage Unit
,” Heat Transfer Eng.
, 30
(6
), pp. 506
–515
.10.1080/0145763080252927139.
Jack
, M. W.
, and Wrobel
, J.
, 2009
, “Thermodynamic Optimization of a Stratified Thermal Storage Device
,” Appl. Therm. Eng.
, 29
(11–12
), pp. 2344
–2349
.10.1016/j.applthermaleng.2008.11.02140.
Kousksou
, T.
, El Rhafiki
, T.
, Arid
, A.
, Schall
, E.
, and Zeraouli
, Y.
, 2008
, “Power, Efficiency, and Irreversibility of Latent Energy Systems
,” J. Thermophys. Heat Transfer
, 22
(2
), pp. 234
–239
.10.2514/1.3122741.
Mawire
, A.
, McPherson
, M.
, and van den Heetkamp
, R. R. J.
, 2009
, “Thermal Performance of a Small Oil-In-Glass Tube Thermal Energy Storage System During Charging
,” Energy
, 34
(7
), pp. 838
–849
.10.1016/j.energy.2009.02.01642.
Hotz
, N.
, Zimmerman
, R.
, Weinmueller
, C.
, Lee
, M.-T.
, Grigoropoulos
, C. P.
, Rosengarten
, G.
, and Poulikakos
, D.
, 2010
, “Exergetic Analysis and Optimization of a Solar-Powered Reformed Methanol Fuel Cell Micro-Powerplant
,” J. Power Sources
, 195
(6
), pp. 1676
–1687
.10.1016/j.jpowsour.2009.09.05543.
Electricity Storage Association, Technologies Database
, 2009
, http://www.electricitystorage.org/site/technologies/technology_comparisons44.
Hotz
, N.
, Pan
, H.
, Grigoropoulos
, C. P.
, and Ko
, S. H.
, 2010
, “Exergetic Analysis of Solar-Powered Hybrid Energy Conversion and Storage Scenarios for Stationary Applications
,” 4th International Conference on Energy Sustainability (ASME ES2010)
, Phoenix
, AZ
, May 17–22
, ASME
Paper No. ES2010-90255, pp. 879
–888
. 10.1115/ES2010-9025545.
Renon
, H.
, Eckert
, C. A.
, and Prausnitz
, J. M.
, 1968
, “Liquid-Liquid and Vapor-Liquid Equilibria for Binary and Ternary Systems With Dibutyl Ketone Dimethyl Sulfoxide N-Hexane and 1-Hexene
,” Ind. Eng. Chem. Process Des. Dev.
, 7
(2
), pp. 220
–225
.10.1021/i260026a01146.
Renon
, H.
, Eckert
, C. A.
, and Prausnitz
, J. M.
, 1967
, “Molecular Thermodynamics of Simple Liquids
,” Ind. Eng. Chem. Fundam.
, 6
(1
), pp. 52
–58
.10.1021/i160021a00847.
Renon
, H.
, and Prausnitz
, J. M.
, 1968
, “Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures
,” AIChE J.
, 14
(1
), pp. 135
–144
.10.1002/aic.69014012448.
Horstmann
, S.
, Mougin
, P.
, Lecomte
, F.
, Fischer
, K.
, and Gmehling
, J.
, 2002
, “Phase Equilibrium and Excess Enthalpy Data for the System Methanol+2,2’-Diethanolamine Plus Water
,” J. Chem. Eng. Data
, 47
(6
), pp. 1496
–1501
.10.1021/je020085e49.
Moran
, M. J.
, and Shapiro
, D. N.
, 1999
, Fundamentals of Engineering Thermodynamics
, 4th ed., Wiley
, New York
.50.
American Institute of Chemical Engineers/Design Institute for Physical Properties
, 2009
, DIPPR® Project 801—Evaluated Standard Thermophysical Property Values, Full Version.51.
Zimmerman
, R.
, Morrison
, G.
, and Rosengarten
, G.
, 2008
, “A Solar Powered Microreactor for Hydrogen Production by Methanol Reforming
,” Proceedings of ASME 2nd International Conference on Energy Sustainability
, Jacksonville, FL
, ASME
Paper No. ES2008-54202, pp. 391
–396
. 10.1115/ES2008-5420252.
Kahlich
, M. J.
, Gasteiger
, H. A.
, and Behm
, R. J.
, 1999
, “Kinetics of the Selective Low-Temperature Oxidation of CO in H2-Rich Gas Over Au/Α-Fe2O3
,” J. Catal.
, 182
, pp. 430
–440
.10.1006/jcat.1998.233353.
RIX Industries, Benicia, CA
, http://www.rixindustries.com54.
PDC Machines, Warminster, PA
, http://www.pdcmachines.com55.
Suction Gas Engine MFG, Tokyo, Japan
, http://www.suction.co.jp56.
Canadian Purcell Machinery, Eastport, ID
, http://www.canadianpurcell.com57.
Gurau
, V.
, Barbir
F.
, and Liu
, H. T.
, 2000
, “
An Analytical Solution of a Half-Cell Model for PEM Fuel Cells
,” J. Electrochem. Soc.
, 147
(7
), pp. 2468
–2477
. 10.1149/1.139355558.
Springer
, T. E.
, Zawodzinski
, T. A.
, and Gottesfeld
, S.
, 1991
, “Polymer Electrolyte Fuel-Cell Model
,” J. Electrochem. Soc.
, 138
(8
), pp. 2334
–2342
.10.1149/1.208597159.
Press
, W. H.
, 1976
, “Theoretical Maximum for Energy From Direct and Diffuse Sunlight
,” Nature
, 264
, pp. 734
–735
.10.1038/264734a060.
Edgerton
, R. H.
, 1980
, “Second Law and Radiation
,” Energy
, 5
, pp. 693
–707
.10.1016/0360-5442(80)90089-4Copyright © 2012 by ASME
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