Membrane microfiltration is a promising technology that has been shown to extend metalworking fluid (MWF) life by eliminating contaminants while allowing the fluid to stay in use. However, the efficacy of this technology is compromised by the clogging of the filter pores in a process known as membrane fouling. In this paper the fouling issue is addressed by the development of a semi-synthetic MWF specifically designed to not foul microfiltration membranes. The composition of the designed MWF is discussed and compared with a commercial MWF. Cross-flow microfiltration fouling tests were carried out in low-pressure, high-velocity conditions on ceramic α-alumina membranes. Several common MWF components are shown not to be factors of membrane fouling on these membranes. The flux of the designed fluid was found to reach an immediate steady state at about twice the value of the steady-state flux of the tested commercial fluid. Scanning electron microscope imaging was used to further evaluate membrane fouling by each fluid. The machining capabilities of the designed fluid were examined in terms of cutting forces and machining temperature.

1.
van Antwerpen
,
F.
, 2000, “
Removal Fluids on the Move
,”
Coolants/Lubricants for Metal Cutting & Grinding: Technology & Market Outlook 2000
,
Gorham Advanced Materials, Inc.
, Chicago, IL.
2.
Marano
,
R. S.
,
Cole
,
G. S.
, and
Craudner
,
K. R.
, 1991, “
Particulate in Cutting Fluids: Analysis and Implications in Machining Performance
,”
Lubr. Eng.
0024-7154,
47
, pp.
376
382
.
3.
Abanto
,
M.
,
Byers
,
J.
, and
Noble
,
H.
, 1994, “
The Effect of Tramp Oil on Biocide Performance in Standard Metalworking Fluids
,”
Lubr. Eng.
0024-7154,
50
, pp.
732
737
.
4.
Skerlos
,
S. J.
,
Rajagopalan
,
N.
,
DeVor
,
R. E.
,
Kapoor
,
S. G.
, and
Angspatt
,
V. D.
, 2000, “
Ingredient-Wise Study of Flux Characteristics in the Ceramic Membrane Filtration of Uncontaminated Synthetic Metalworking Fluids, Part 1: Experimental Investigation of Flux Decline
,”
ASME J. Manuf. Sci. Eng.
1087-1357,
122
(
4
), pp.
739
745
.
5.
Belfort
,
G.
,
Davis
,
R. H.
, and
Zydney
,
A. L.
, 1994, “
The Behavior of Suspensions and Macromolecular Solutions in Cross-Flow Microfiltration
,”
J. Membr. Sci.
0376-7388,
96
, pp.
1
58
.
6.
Skerlos
,
S. J.
,
Rajagopalan
,
N.
,
DeVor
,
R. E.
,
Kapoor
,
S. G.
, and
Angspatt
,
V. D.
, 2000, “
Ingredient-Wise Study of Flux Characteristics in the Ceramic Membrane Filtration of Uncontaminated Synthetic Metalworking Fluids, Part 2: Analysis of Underlying Mechanisms
,”
ASME J. Manuf. Sci. Eng.
1087-1357,
122
(
4
), pp.
746
752
.
7.
Skerlos
,
S. J.
,
Rajagopalan
,
N.
,
DeVor
,
R. E.
,
Kapoor
,
S. G.
, and
Angspatt
,
V. D.
, 2001, “
Microfiltration of Polyoxyalkylene Metalworking Fluid Lubricant Additives Using Aluminum Oxide Membranes
,”
ASME J. Manuf. Sci. Eng.
1087-1357,
123
(
4
), pp.
692
699
.
8.
Gilmer
,
J. A.
,
Eppert
,
J. J.
, and
Rajagopalan
,
N.
, 2005, “
Formulation and Testing of a Microfiltration Compatible Synthetic Metalworking Fluid
,”
J. Membr. Sci.
0376-7388,
256
(
1–2
), pp.
18
28
.
9.
Mahdi
,
S. M.
, and
Skold
,
R. O.
, 1990, “
Field Testing of a Model Waterbased Metalworking Fluid Designed for Continuous Recycling Using Microfiltration
,”
Lubr. Eng.
0024-7154,
47
, pp.
653
659
.
10.
Mahdi
,
S. M.
, and
Skold
,
R. O.
, 1991, “
Experimental Study of Membrane Filtration for the Recycling of Synthetic Waterbased Metalworking Fluids
,”
Lubr. Eng.
0024-7154,
24
,
389
395
.
11.
Byers
,
J. P.
, ed., 1994,
Metalworking Fluids
,
Marcel Dekker
, New York.
12.
Rajagopalan
,
N.
,
Rusk
,
T.
, and
Dianovsky
,
M.
, 2004, “
Purification of Semi-synthetic Metalworking Fluids by Microfiltration
,”
Trib. Lub. Tech.
,
60
, pp.
38
44
.
13.
Wentz
,
J. E.
,
Kapoor
,
S. G.
,
DeVor
,
R. E.
, and
Rajagopalan
,
N.
, 2005, “
Experimental Investigation of Membrane Fouling Due to Microfiltration of Semi-Synthetic Metalworking Fluids
,”
Trans. NAMRI/SME
1047-3025,
33
, pp.
281
288
.
14.
Zhao
,
F.
,
Urbance
,
M.
, and
Skerlos
,
S.
, 2004, “
Mechanistic Model of Coaxial Microfiltration for Semi-synthetic Metalworking Fluid Microemulsions
,”
ASME J. Manuf. Sci. Eng.
1087-1357,
126
(
3
), pp.
435
444
.
15.
Ma
,
H. M.
,
Bowman
,
C. N.
, and
Davis
,
R. H.
, 2000, “
Membrane Fouling Reduction by Backpulsing and Surface Modification
,”
J. Membr. Sci.
0376-7388,
173
(
2
), pp.
191
200
.
16.
Ezzati
,
A.
,
Gorouhi
,
E.
, and
Mohammdi
,
T.
, 2005, “
Separation of Water in Oil Emulsions Using Microfiltration
,”
Desalination
0011-9164,
185
, pp.
371
382
.
17.
Rusk
,
T.
, and
Rajagopalan
,
N.
, 2003, “
Evaluation of Aged and Recycled Metalworking Fluids by the Tapping Torque
,”
Lubr. Eng.
0024-7154,
59
, pp.
10
14
.
18.
Greeley
,
M. H.
, 2002, “
Evaluations of Metalworking Fluid Functionality Using a Novel Drilling-Based Methodology
,” Masters thesis, University of Illinois at Urbana-Champaign, Urbana, IL.
19.
Zhao
,
F.
, 2005, “
Microfiltration Recycling of Semi-Synthetic Metalworking Fluids: Modeling and Formulation Design
,” Ph.D. thesis, University of Michigan, Ann Arbor, MI.
20.
Nunn
,
C. C.
, 1981, “
Equilibrium Adsorption onto Alumina from Some Solubilized Systems
,” Ph.D. thesis, University of Texas at Austin, Austin, TX.
21.
Hirva
,
P.
, and
Pakkanen
,
T. A.
, 1992, “
The Interaction of Amine Bases on the Lewis Acid Sites of Aluminum Oxide—a Theoretical Study
,”
Surf. Sci.
0039-6028,
277
, pp.
389
394
.
22.
Kasprzyk-Hordern
,
B.
, 2004, “
Chemistry of Alumina, Reactions in Aqueous Solution and its Application in Water Treatment
,”
Adv. Colloid Interface Sci.
0001-8686,
110
, pp.
19
48
.
23.
Verewey
,
E. J. W.
, and
Overbeek
,
J. T. G.
, 1948,
Theory of Stability of Lyophobic Colloids
,
Elsevier
, Amsterdam.
24.
Johnson
,
T. L.
, 1990, “
A Novel Oxazoline Compound for use in Metalworking Fluid Formulations
,”
Lubr. Eng.
0024-7154,
46
, pp.
279
284
.
25.
Silliman
,
J. D.
, 1992,
Cutting and Grinding Fluids: Selection and Application
,
SME
, Dearborn, MI.
26.
Ramachandran
,
V.
,
Venkatesan
,
R.
,
Tryggvason
,
G.
, and
Fogler
,
H. S.
, 2000, “
Low Reynolds Number Interactions Between Colloidal Particles Near the Entrance to a Cylindrical Pore
,”
J. Colloid Interface Sci.
0021-9797,
229
, pp.
311
322
.
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